Do perturbation theory around a 0th order degenerate state.
Then
If partially splits the degeneracy, then the particular basis you
choose in the degenerate subspace is important.
Define projectors:
,
P is the projector of the degenerate subspace. In the degenerate
subspace:
.
Define ,
. Solving
exactly is first order degenerate perturbation
theory. Solving
is second order.
Solutions of which are less degenerate... Then higher order approximations
don't have to worry about degeneracy.
And
applications: