The schrodinger equation in 3-d is:
H Psi = i hb d/dt (Psi)
with H=1/2m*p^2+V(r_x,r_y,r_z)=1/2m * (p_x^2+p_y^2+p_z^2) + V(r_x,r_y,r_z)
p_i=hb/i * d/dx
More concisely, H=-hb^2/2m del^2 + V(r_x,r_y,r_z)
Typically, the differential equation for Psi will quantize as:
H Psi_n = E_n Psi_n
with E_n= quantized energy states indexed by n and Psi_n = an eigenstate.
If E<0 => discrete spectrm while E>0 => continuous spectrum.
If V-> 0 as r -> infinity => Psi -> 0 as r -> infinity, something necessary for normalization.
An analysis of the schrodinger equation in spherical coordinates indicates that it can be written as:
H=p_r^2/2m + L^2/2mr^2 +V(r)
This is solved by the method of seperation of variables, first seperation
into Psi(r,theta,phi)=R(r)Y(theta,phi)
Then into Y(theta,phi)=P(theta) Phi(phi)
The BC on phi is that Phi(phi)=Phi(phi+2 PI) => Phi(phi)=1/(2 PI)^.5 e^(i m phi) for m in Z
P(theta) is transformed into P(cos(theta)). Demanding non-infinite solutions => associated Legendre polynomials are a solution.
The solution of the radial equation is Hermite polynomials.