To draw the mouth, you should use the function canvas.create_arc(...) of Tkinter with the optional parameters style and extent. Try running the code below to understand how this works. (For more information about this function read the documentation here.)
from cmu_112_graphics import *
import math
def redrawAll(app, canvas):
cx = app.width / 2
cy = app.height / 2
x0 = cx - 100
x1 = cx + 100
y0 = cy - 50
y1 = cy + 50
e = -180
canvas.create_rectangle(x0, y0, x1, y1, outline = 'red')
canvas.create_oval(x0, y0, x1, y1, outline = 'blue')
canvas.create_arc(x0, y0, x1, y1,
outline="green", width = 5, style="arc", extent=e)
runApp(height = 400, width = 400)