More precisely, it is the electron interaction with zero-point energy of the quantized electromagnetic field.
To first order, this is interactions like emission and absorption
of a photon. This is consistent if and
. Energy shifts are infinite...
wheeee.... The only thing that matters is energy differences, so the
infinities get subtracted.
The lamb shift is . This is nonzero for s-wave states. This is about
. so
The lamb shift further splits from